There's a ton of new stuff in Visual Studio Team System 2008. I've copied the content list from the online help library below, so you can jump directly into the library from here.
Team Foundation
Team Foundation Build Build Definitions Continuous Integration of Builds Scheduled Builds Build Agents HTTPS and Secure Sockets Layer (SSL) for Build New Properties for Customizing Team Foundation Build New Tasks and Targets for Customizing Team Foundation Build Team Foundation Source Control Destroy Get Latest on Check-Out Annotating Files Comparing Folders Team Foundation Work Item Tracking Team Foundation Server Management Architecture Edition Design Application Systems by Using a Top-Down Approach Conform .NET Web Service Endpoints to WSDL Files Generate ASP.NET Web Application Projects for ASP.NET Applications Save, Import, and Export Custom Prototypes Select From Multiple .NET Framework Versions Select From Multiple Office Versions Database Edition Specify Table and Index Options Developer Edition Code Analysis Rules Extension and Enhancement Spelling Checker with Custom Dictionary Support Better Control over Suppression from the Error List Auto-Suppress Generated Code Option Code Analysis Policy Improvements Code Metrics Profiling Tools 64-Bit Support Full Allocation Stacks Line-level Sampling Data Report Noise Reduction Runtime Control Filtered Analysis Compare Reports Improved Chip Counter Support Windows Counter Support Compressed Report Files Hot Path Copy Report View Data to HTML Windows Communications Foundation Support Load and Web Test Integration in Visual Studio Team Suite Test Edition Testing Methods of Your Code Use Unit Tests in Visual Studio Professional Edition Run Unit Tests More Easily Use Inheritance Between Test Classes Run Unit Tests on Devices Create Host Adapters Improved Unit Test Data Binding Web Testing Web Sites Call a Web Test From Another Web Test Improved Web Test Data Binding Improved Web Test Features Load Testing Control Load Modeling Improved Load Test Analyzer Views Improved Load Test Results Repository Management Published Schema for XML Files
Team Foundation Build
Build Definitions
Continuous Integration of Builds
Scheduled Builds
Build Agents
HTTPS and Secure Sockets Layer (SSL) for Build
New Properties for Customizing Team Foundation Build
New Tasks and Targets for Customizing Team Foundation Build
Team Foundation Source Control
Destroy
Get Latest on Check-Out
Annotating Files
Comparing Folders
Team Foundation Work Item Tracking
Team Foundation Server Management
Architecture Edition
Design Application Systems by Using a Top-Down Approach
Conform .NET Web Service Endpoints to WSDL Files
Generate ASP.NET Web Application Projects for ASP.NET Applications
Save, Import, and Export Custom Prototypes
Select From Multiple .NET Framework Versions
Select From Multiple Office Versions
Database Edition
Specify Table and Index Options
Developer Edition
Code Analysis
Rules Extension and Enhancement
Spelling Checker with Custom Dictionary Support
Better Control over Suppression from the Error List
Auto-Suppress Generated Code Option
Code Analysis Policy Improvements
Code Metrics
Profiling Tools
64-Bit Support
Full Allocation Stacks
Line-level Sampling Data
Report Noise Reduction
Runtime Control
Filtered Analysis
Compare Reports
Improved Chip Counter Support
Windows Counter Support
Compressed Report Files
Hot Path
Copy Report View Data to HTML
Windows Communications Foundation Support
Load and Web Test Integration in Visual Studio Team Suite
Test Edition
Testing Methods of Your Code
Use Unit Tests in Visual Studio Professional Edition
Run Unit Tests More Easily
Use Inheritance Between Test Classes
Run Unit Tests on Devices
Create Host Adapters
Improved Unit Test Data Binding
Web Testing Web Sites
Call a Web Test From Another Web Test
Improved Web Test Data Binding
Improved Web Test Features
Load Testing
Control Load Modeling
Improved Load Test Analyzer Views
Improved Load Test Results Repository Management
Published Schema for XML Files
What's New in Visual Studio Team System