This ASP.NET 2.0 webcast series is specifically built to help PHP, JSP, and ColdFusion developers extend their skill sets to include ASP.NET -- know anyone who is interested?  Let them know...  Or if you just want to sharpen your skills?  Either way, check out http://www.learn2asp.net/ -- attend 3 webcasts and get a bunch of great free stuff including VS2005, a book, hosting and more.