Erik Mork has put together a nice series of posts and web casts as an introduction to Prism for Silverlight.  Here is what he has available:

Videos

Intro to Silverlight Prism - http://development-guides.silverbaylabs.org/Video/Silverlight-Prism

Testing/Module Catalog/Unity - http://development-guides.silverbaylabs.org/Video/Modularity-in-Prism

Regions (including Region Scope, Region Adapter and Region Context) - http://development-guides.silverbaylabs.org/Video/Prism-Regions

Commanding (including creating new commands) - http://development-guides.silverbaylabs.org/Video/Prism-Commands

Eventing - http://development-guides.silverbaylabs.org/Video/Prism-Eventing

Podcasts

What is Prism - http://www.sparklingclient.com/prism-in-silverlight/

Modularity in Prism - http://www.sparklingclient.com/modularity-in-prism/

When to use Prism - http://www.sparklingclient.com/when-to-use-prism/

Regions in Prism - http://www.sparklingclient.com/regions-in-prism/

View or Presenter First? - http://www.sparklingclient.com/which-comes-first-the-view-or-the-viewmodel/

Commanding - http://www.sparklingclient.com/commanding-in-prism/

Event Aggregator - http://www.sparklingclient.com/prisms-event-aggregator/

 
Blog Posts

10 Things to Know about Silverlight Prism (overview of all resources) - http://www.sparklingclient.com/prism-silverlight/

Downloading and Building Prism - http://www.sparklingclient.com/downloading-and-building-prism/

 

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