Nick blogged this a while back about how ISV's could make Microsoft aware of their products. This is once of my FAQ's and there's a well defined process to follow, due to the complexity of the intellectual property laws. There isn't a simple way of making the relevant business groups aware of your solution or product without going through a more controlled assessment.
More detail: Microsoft has established a comprehensive review process to evaluate third party business proposals. The Opportunity Management Centre (OMC) provides you a safe and effective way to engage Microsoft with your business proposal and ensures you receive timely feedback and relevant resources. This site is designed to help you efficiently submit a business proposal for consideration by Microsoft.
How the review process works:
For additional information or details about the process, please review the FAQ or other program resources listed in the left navigation bar. Visit https://members.microsoft.com/omc/welcome.aspx for more information.