When you use WCF, you take for granted a lot of the infrastructure that actually moves data from place to place. TCP/IP is the backbone of the Internet, allowing computers with different hardware running different software to communicate with each other. TCP/IP is more than just a single protocol though; it's actually a suite of protocols stacked on top of each other in layers. There are various ways to describe the protocol layers of a networking stack. The OSI model is a 7-layer stack that many people think is unnecessarily complicated. I'm already going to unnecessarily complicate things by including WCF in the picture, so I'll use a slightly simpler traditional networking stack underneath.
Eventually though, you should reach the end of the channel stack and ascend upward into your application. There's no telling what layer number your application is going to have.
TCP and IP are only two of the protocols that make up the TCP/IP protocol suite. You'll have to wait until Monday to find out about the other protocols that keep the Internet working.
Next time: How TCP/IP Works, Part 2: Protocols