Here is a great article that tells you how to resolve documents that are stuck in the Microsoft Office Document Cache (Uploader) when it is convinced that you have a document in there to upload that doesn't exist.

  • Close all Office programs.
  • Click the Ctrl + Shift + Esc keys to open the Task Manager.
  • On the Processes tab, select MSOSYNC.EXE, click End Process, and then close the Task Manager.
  • Navigate to %userprofile% \AppData\Local\Microsoft\Office\14.0\ in Microsoft Office 2010 or %userprofile% \AppData\Local\Microsoft\Office\15.0\ in Microsoft Office.
  • Rename or delete the OfficeFileCache folder.