WS-BPEL is very much a subset of what can be represented using WF. Think of WF as a "graph of activities" that can be transformed to virtually any workflow standard. I'll try to post a similar comparison between WS-BPEL 2.0 and XPDL 2.0 later this week.
BPEL Activity
WF Activity
<receive>
Workflow start or WebServiceReceive
<reply>
Workflow finish or WebServiceResponse
<sequence>
Sequence
<assign>
Code
<while>
While
<if>, <elseif>
IfElse
<invoke>
InvokeWebService
<scope>
Scope
<flow>
Parallel
<pick>
Listen
<throw>
Throw
<compensate>
Compensate
<exit>
Terminate
<wait>
Delay , Suspend
<faultHandlers>
ExceptionHandler/ExceptionHandlers