At Tech Ed 2007, I gave another tips and tricks talk for working with the C# IDE. Here's the list of tips that I presented (it's a cleaner version of Tips.cs that I used during the talk).
Tips for Understanding Code
1) [VS 2008] Target Multiple Versions of the Framework
2) C# Development Settings
3) Add New Item
4) Class Designer
5) Active File Drop-down (Ctrl + Alt + Down Arrow)
6) Collapse to Definition (Ctrl+M, 0)
7) Go to Definition (F12)
8) GTD Navigation Stack (Ctrl+Shift+7, Ctrl+Shift+8)
9) Find All References (Shift+F12)
10) Iterate through List Window (F8)
11) Find Combo Box (Ctrl + /)
Tips for Writing and Modifying Code
12) Rename
13) Code Snippets
14) Invoke Smart Tag (Ctrl + .)
15) Add Using
16) Generate Method Stub
17) Snippets for Code Generation
18) [VS 2008] IntelliSense for Object Initalizers
19) [VS 2008] IntelliSense for Query Expressions
20) [VS 2008] Quick Info for C# 3.0 Understanding
21) IntelliSense Customization
22) [VS 2008] Customize Formatting Style
23) Customize your Context Menu
24) [VS 2008] Debugging Query Expressions
25) [VS 2008] Organize Usings