I gathered a list of leaning resources on Microsoft products, solutions and technologies and then tought they might be useful to others too. Following are links to free training, videos, webcasts and virtual labs that will hopefully satisfy all of your knowledge needs. If you have links to additional learning resources let me know and I will add them to the list.
Microsoft Showcasehttp://www.microsoft.com/showcase/en/us/default.aspx
Channel 9http://channel9.msdn.com/
Training Courses (identity management, Office 2010, SharePoint 2010, SilverLight 4, Visual Studio 2010, Windows Azure, Windows Phone 7, etc.)http://channel9.msdn.com/Learn/Courses
MSDN How Do I videoshttp://msdn.microsoft.com/en-us/bb629407.aspx
TechNet How Do I videoshttp://technet.microsoft.com/en-us/cc138021.aspx
MIX 2010 videoshttp://live.visitmix.com/Videos
TechEd Onlinehttp://www.msteched.com/
Microsoft TechDays 2010 Belgiumhttp://www.microsoft.com/belux/techdays/2010/
Microsoft DevDays 2010 Netherlandshttp://www.devdays.nl/Agenda.aspx?pid=66&lang=en (download slide decks only)
Windows 7 videoshttp://windows.microsoft.com/en-US/windows7/products/videos
PDC 2010 (professional developer conference)http://player.microsoftpdc.com/schedule/sessions
PDC 2009 sessions on-demandhttp://www.microsoftpdc.com/2009
ASP.NEThttp://www.asp.net/get-started
SilverLighthttp://www.silverlight.net/learn/
WPF & Windows Formshttp://windowsclient.net/getstarted/
Microsoft Expressionhttp://expression.microsoft.com/en-us/cc136522.aspx
Microsoft Surfacehttp://www.microsoft.com/surface/en/us/Pages/Technical/Training.aspx
Virtual Labs (MSDN & TechNet Virtual Labs)http://www.microsoft.com/events/vlabs/default.mspx
MICROSOFT OFFICE
How Do I Videos for Office Developershttp://msdn.microsoft.com/en-us/office/bb496949.aspx
Office Developer How-to Centerhttp://msdn.microsoft.com/en-us/office/bb266408.aspx
Office 2010 traininghttp://office.microsoft.com/en-us/training/
Backstage with Office 2010http://www.office2010themovie.com/
WEBCASTS and VIDEOS
On-demand webcastshttp://www.microsoft.com/events/webcasts/ondemand.mspx
Monthly Archived Webcastshttp://www.microsoft.com/events/webcasts/library/default.mspx
Online Media Series: webcasts, videos, virtual labs and podcasts organized based on technology and on job role (dev, IT professional, IT executive, business executive, etc.)http://www.microsoft.com/events/series/default.aspx