When damsels are in distress, there is Superman! And when Team System customers are in distress there are the VS Team System Rangers. Working with Microsoft Consultancy services, the Product teams and customers they have collated and given you a single point of contact for all VSTS documentation. Customers repeatedly complained that 'Scattered documentation' was one of the biggest problems they had and the Rangers have done a fantastic job addressing this problem.
Additionally it delivers education in a Consulting and Best Practices manner.
Check it out at:
Operations Guidance for Team Foundation Server
Hope this helps!