Guides

SharePoint 2010 Overview Evaluation Guide

http://go.microsoft.com/?linkid=9727161

SharePoint 2010 Walkthrough Guide

http://go.microsoft.com/?linkid=9727427

Microsoft SharePoint Server 2010 Evaluation Guide For IT Professionals

http://go.microsoft.com/?linkid=9727162

Microsoft SharePoint 2010 Professional Developer’s Evaluation Guide

http://go.microsoft.com/?linkid=9727163

Trainings:

SharePoint 2010 Training Kit

http://channel9.msdn.com/learn/courses/SharePoint2010Developer/

Office 2010 Training kit:

http://channel9.msdn.com/learn/courses/Office2010

VHD

SharePoint 2010 and Office 2010 evaluation VHD

http://www.microsoft.com/downloads/details.aspx?FamilyID=751fa0d1-356c-4002-9c60-d539896c66ce&displaylang=en