The videos of the VSLive Keynotes are on the Fawcette web site.
Soma announced VS 2005 Standard in his keynote and has the latest dev tools roadmap. There is also a seperate link to the reg-free COM demo in his keynote. Reg-free COM is coming in Whidbey and is an important piece of ClickOnce. This lets you install (on a Windows XP machine) any COM components in your application without having to write to the Registry. Dave Templin of the VB team is working on an article explaining this in detail.
Dave Mendlen, who is now the Director of Web Services Technical Marketing, talks about Web services and SOA in his keynote. This is a good opportunity for you to get an understanding of what these are going to mean to VS developers today and over the next few years.