Now that the WCF REST Starter Kit is out I'm happy to say that we have provided some great resources for learning all about it.
Aaron Skonnard has put together a terrific set of screencasts for endpoint.tv to give you a great introduction to REST with WCF and the WCF REST Starter Kit
From the PDC we have Steve Maine and Rob Bagby doing an excellent presentation
And if you want to get hands-on we have a set of hands on labs for you to try out as well.
I've just been told that my REST talk here at Tech-Ed Developers in Barcelona is so popular that they have scheduled a second session so you can take your pick.
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With the recent release of the WCF REST Starter Kit , Microsoft made implementing REST services via WCF