Ted Pattison and Andrew Connell have a bunch of Learning SharePoint 2010 content up on Channel 9.
I can say, having attended Ted’s classes in the past, he’s one of the best to learn SharePoint development from. He’s been at the forefront of getting to the reality of how to build things while working with the guidelines, rules, constraints of a “managed” platform such as SharePoint.
If you get a chance take a look at these videos – even better, if you can attend in person, check out http://www.criticalpathtraining.com/ for classes.
SharePoint 2010 Developer | Learn | Channel 9