We have some courses available on Channel 9 for self paced learning:

Windows Azure - http://channel9.msdn.com/learn/courses/Azure/

Windows Server HPC - http://channel9.msdn.com/learn/courses/HPCLearningCourse/

Identity Developer Training course - http://channel9.msdn.com/learn/courses/IdentityTrainingCourse/

Office 2010 Workshop - http://channel9.msdn.com/learn/courses/Office2010/

SharePoint 2010 Developer - http://channel9.msdn.com/learn/courses/SharePoint2010Developer/

Silverlight 4 Training Course - http://channel9.msdn.com/learn/courses/Silverlight4/

Visual Studio 2010 & .NET Framework 4 - http://channel9.msdn.com/learn/courses/VS2010/

Windows 7 Online - http://channel9.msdn.com/learn/courses/Windows7/

Windows Server 2008 R2 Developer Training - http://channel9.msdn.com/learn/courses/WindowsServer2008R2/