A configurable glow effect can be achieved for Silverlight 2 Beta 1 with the use of the Grid control and gradient fills. This will achieve the effect for rectangular and rounded rectangular controls.
The GlowBox control is composed of a Canvas containing a Grid which is used to build the glow and a ContentPresenter.
The grid contains 8 rectangles with linear or radial gradients. The gradient stop is adjusted to achieve varying degrees of rounding.
A few things that need to be added :
The lastest code for this effect can be found in InnerGlow Post.