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The MPR website has been updated to include Office 365 under the Develop Tab. Here are some of the resource available at the site:
Learn in-depth about the individual services by watching these videos for developers:
TechEd 2011 Office 365 Greatest Hits
Office 365 Training Course on MSDN: We released this training course along with the public Beta. The course includes 7 sessions, over 10 hours of video, and 16 labs as both an offline training kit as well as an online training course on MSDN. We’ll be including the School of Fine Art demo with the GA version of the kit. Stay tuned for more details!
Getting Your Own Office 365 Beta Account: Sign up at http://office365.com to get access to the Beta.