Here is a draft of things I was thinking about(Performed by stars from the dev team), what do you think?

Intoduction to Windows Presentation Framework - Getting to know the key concepts of the nex ration UI Technology
Interoperability between Windows Presentation Foundation and Windows Forms
Windows Communication Foundation - Part 1 - Introduction
Windows Communication Foundation - Part 2 - Moving to WCF from Current Technologies
Windows Workflow Foundation - Part 1 - Introduction
Windows Communication Foundation - Part 1 - IIntegrating WWF into your current projects
A Recap on Office 2003 Development
Preparing for Office 12 Development
Managing your daily build with Team System
Team System - The Source Control Prespective
Team System - How to effectivly test your application
Team System End To End - Application Life Cycle Managment
Team System - How to effectivly read reports
Team System - Expressing your development process thru Team System
Things you didn't know about Mobile Devices Development
From SQL Express to SQL Server Data Center Edition - The developer Prespective
SQL Server Development Tecnologies
The .NET Language Integrated Query Framework: An Overview
Using the .NET Language Integrated Query Framework with Relational Data
Advanced Windows Form Topics - Part 1
Advanced Windows Form Topics - Part 2
Advanced ASP.NET 2.0 - Part 1
Advanced ASP.NET 2.0 - Part 2
Levaraing extenstions in VS as a platform for developers
Microsoft Integration Technologies: When to Use What
Writing Secured Code