Here's a great set of stuff to get you started using some of the new controls/features in Windows Forms 2.0!

Client Settings
  [
FAQ | Feature Page ]
Data Binding 
   [
FAQ | Sample and Demo | Feature Page  ]
DataGridView
   [
FAQ | Sample and Demo | Feature Page ]
Designer              
   [
FAQ  | Presentation | Sample and Demo ]
Layout Features    
   [
FAQ  | Presentation | Sample and Demo | Feature Page ]
MaskedTextBox    
   [
FAQ | Presentation | Sample and Demo | Feature Page ]
SplitContainer       
   [
FAQ | Sample and Demo | Feature Page ]
ToolStrip              
   [
FAQ | Presentation | Sample and Demo | Feature Page ]
WebBrowser         
   [
FAQ | Sample and Demo | Feature Page ]
WF/WPF Interop 
   [
FAQ | Sample and Demo ]