Starting with a blank sheet of Expression Blend paper...
A few weeks ago I recorded an interview with Martin Grayson about what you do when you start up Expression Blend for the first time. You know the kind of thing... new tool... blank screen... Ahhhhh... PANIC!
Thankfully Martin did a great job of responding to my dumb questions (I was trying to play dumb - honest :-) ) and showing how to build a pretty compelling WPF application with no code... ideal for us Architect types :-)
Anyway the 4 short videos are up on Channel 9 now, so please take a look and let me know if this kind of thing is useful.
Real-world WPF: Introduction to Blend (Part1)
Real-world WPF: Introduction to Blend (Part2)
Real-world WPF: Introduction to Blend (Part3)
Real-world WPF: Introduction to Blend (Part4)