This looks like a pretty good series from Notion Solutions, one of the premier VSTS consulting and training firms.

http://msdn2.microsoft.com/en-us/bb905051.aspx

Webcast Series: Essential Visual Studio Team System 2008

Driving Predictability, Visibility, and Control into your Software Development Process

Want to learn more about Visual Studio Team System without having to leave your own home or office? Simply register to attend our weekly VSTS webcast series. Every Thursday we deliver one or two 1-1/2 hour interactive webcast sessions designed to provide you with a solid understanding of how Team System's role-based tools support the entire software development team, including architects, developers, testers, project managers, and other business stakeholders.

  • Visual Studio Team System 2008 Overview
  • Rosario Overview: Future VSTS Features
  • Essential Team Foundation Server
  • Essential Team System for QA Professionals
  • Essential Team System for Developers
  • Essential Team System for Database Developers