Here is a good MSDN tech article which demonstrate using custom MessageInspector to validate WCF xml message: #How to: Perform Message Validation with Schema Validation in WCF http://msdn.microsoft.com/en-us/library/cc949095.aspx
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[WCF]How to inspect and modify WCF message via custom MessageInspector Recently I received some questions about how to modify message content of WCF operation calls. By checking the WCF extensibility, it seems “ MessageInspector ” is the proper one for
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